御食い初め[okuizome] weaning ceremony
為初め[shisome] outset
為初める[shisomeru] to begin to do
仮初[karisome] temporary
業界初[gyoukaihatsu] the industry's first ...

月初め[tsukihajime] beginning of month
最初[saisho] beginning
初めに[hajimeni] to begin with (used as an introduction)
初めは[hajimeha] at first
手初めに[tehajimeni] at first

に当たって[niatatte] at the time of (ind. opportunity or situation where something should be done)
一騎当千[ikkitousen] being a match for a thousand
一指当たり[ichiyubiatari] span
一人当たり[hitoriatari] per person
一人当て[hitoriate] per person

引当[hikiate] mortgage
引当金[hikiatekin] reserves
押し当てる[oshiateru] to push (something) against
穏当[ontou] proper
過当[katou] excessive