赧らめる[akarameru] to blush
愧赧[kitan] blushing with embarrassment

赧顔[tangan] blushing (with shyness)

雲鬢花顔[unbinkagan] beautiful woman (metaphorical)
横顔[yokogao] face in profile
温顔[ongan] kindly face
なに食わぬ顔[nanikuwanukao] innocent look
我物顔[wagamonogao] looking or acting as if one owned the place

汗顔[kangan] ashamed
顔から火が出る[kaokarahigaderu] to be extremely embarrassed
顔を顰める[kaowoshikameru] to grimace
顔を潰す[kaowotsubusu] to make somebody lose face