御食い初め[okuizome] weaning ceremony
為初め[shisome] outset
為初める[shisomeru] to begin to do
仮初[karisome] temporary
業界初[gyoukaihatsu] the industry's first ...

月初め[tsukihajime] beginning of month
最初[saisho] beginning
初めに[hajimeni] to begin with (used as an introduction)
初めは[hajimeha] at first
手初めに[tehajimeni] at first

データの先頭[deetanosentou] beginning of data
一頭[ittou] one large animal (horses, cattle, etc.)
一頭立て[ittoudate] one-horse (carriage)
咽頭[intou] pharynx
駅頭[ekitou] station

音頭[ondo] leading a group of people
会頭[kaitou] society president
街頭[gaitou] in the street
核弾頭[kakudantou] nuclear warhead
巻頭[kantou] opening page of book